[Header]
Format=SMU
ver=3
appl=GUMWB32
MR=0
FUEB=0

[Title]
Title='Uncertainty Estimation in Photometric Determination of Phosphorus in Feed'
Description=119
Description[0]='Analysis Procedure'
Description[1]=''
Description[2]='Preparation of the Phosphorus Stock Solution'
Description[3]=''
Description[4]='KH2PO4 (M = 136.09 g/mol, purity more than 99.8%) was dried at 103 °C for 1'
Description[5]='hour. 4447.2 mg of the obtained salt was weighed and transferred to a 1000.0 ±'
Description[6]='0.6 ml volumetric flask and filled to the mark with distilled water. This is'
Description[7]='the phosphorus stock solution.'
Description[8]=''
Description[9]='Preparation of the Calibration Line'
Description[10]=''
Description[11]='From the stock solution standard solutions were made to 100.0 ± 0.3 ml'
Description[12]='volumetric flasks. To these flasks 0.500, 1.000, 2.000, 3.000 and 4.000 ml of'
Description[13]='the stock solution was pipetted and the flasks were filled to the mark. The'
Description[14]='pipetting operations were carried out using graduated pipettes. From the data'
Description[15]='in the manufacturer''s catalogue it appears that for ± 0.5% of the pipetted'
Description[16]='volume can be used as the estimate of the calibration uncertainty. For'
Description[17]='obtaining the calibration line one measurement was made with each of these'
Description[18]='solutions. For the measurement 10.00 ml of the solution was pipetted'
Description[19]='(calibration uncertainty of the pipette ± 0.03 ml) into a small stoppered'
Description[20]='reaction flask. The same pipette was used for pipetting all the standard'
Description[21]='solutions and the sample solution. To eliminate the carryover effect the'
Description[22]='pipette was rinsed two times with the respective solution before pipetting.'
Description[23]='10.00 ml of molybdatovanadate reagent was added (calibration uncertainty of the'
Description[24]='pipette ± 0.03 ml). The same pipette was used for adding the reagent both for'
Description[25]='the calibration solutions and the sample solution. The solution was mixed and'
Description[26]='let stand for 10 minutes. The solution was then transferred to'
Description[27]='spectrophotometric cell (the cell was twice rinsed with the solution before the'
Description[28]='measurement) and the absorbance was measured against blank. The absorbance'
Description[29]='values obtained were: 0.086, 0.173, 0.341, 0.518 and 0.686 AU, respectively for'
Description[30]='the five solutions.'
Description[31]=''
Description[32]='Preparation of the Sample'
Description[33]=''
Description[34]='The amount of sample (that had been thoroughly mixed and sieved) taken for the'
Description[35]='analysis was 2542.1 g. The sample was carefully mixed with 1 g of calcium'
Description[36]='carbonate and ashed in a muffle furnace at 550 °C. The ash was transferred to a'
Description[37]='250 ml beaker with 50 ml of water. 6M HCl solution was added in small batches'
Description[38]='until the bubbling stopped. Then additional 10 ml of 6M HCl was added and the'
Description[39]='contents of the beaker were evaporated to dryness. 10 ml of 1M HNO3 was added'
Description[40]='to the residue and boiled on sand-bath. The resulting liquid was quantitatively'
Description[41]='transferred to 500.0 ± 0.4 ml volumetric flask and filled to the mark with'
Description[42]='water.'
Description[43]=''
Description[44]='Measurement of the Sample Solution'
Description[45]=''
Description[46]='The same method was used for measurement as in the case of the calibration'
Description[47]='standard solutions with the only difference was that before measurement a small'
Description[48]='part of the solution was filtrated and 10 ml taken from the filtrate. The'
Description[49]='reading obtained was 0.474 AU. The same photometer was used for all'
Description[50]='measurements. It has digital display with 3 digits after the comma. From the'
Description[51]='documentation of the photometer the following data were found: "photometric'
Description[52]='reproducibility ± 0.002 AU; stability ± 0.0003 AU/h; baseline stability ± 0.001'
Description[53]='AU/h". These data correspond to a new instrument, but the used photometer was 8'
Description[54]='years old. In addition, with the current method there is the additional source'
Description[55]='of uncertainty, which is far bigger than the purely instrumental repeatability'
Description[56]='- the chemical reaction. Therefore the data on drift and reproducibility were'
Description[57]='determined experimentally in the laboratory (see below).'
Description[58]=''
Description[59]='Parameters Determined Earlier at the Same Laboratory or Obtained from Other'
Description[60]='Sources'
Description[61]=''
Description[62]='1. Repeatability of weighing. By repeated weighing (10 times) of a sample that'
Description[63]='had similar mass to the sample of this work it was found that the repeatability'
Description[64]='standard uncertainty of weighing was u(m, rep) = 0.00017 g (found as standard'
Description[65]='deviation of the masses). The weighing was done as tared weighing, so the'
Description[66]='uncertainty originating from taring operation is included in the uncertainty'
Description[67]='estimate. The repeatability is essentially independent of the mass.'
Description[68]=''
Description[69]='2. Drift of weighing. Drift is more difficult to determine than repeatability.'
Description[70]='The drift is not necessarily the same on different days and if the laboratory'
Description[71]='is not air-conditioned (as is the case in this example) then it depends on the'
Description[72]='season. Based on long-time observations it was found that during 4-5 hours the'
Description[73]='balance drift is no more than ± 0.0002 g.'
Description[74]=''
Description[75]='3. Repeatability of pipetting. For those cases when the repeatability is not'
Description[76]='determined directly at the laboratory, it is safe to assume that the'
Description[77]='repeatability standard uncertainty of pipetting is 0.4% of the pipetted volume.'
Description[78]=''
Description[79]='4. Repeatability of filling volumetric flasks. With all volumetric flasks it is'
Description[80]='assumed that the flask is filled dropwise and the uncertainty is ± 1drop, that'
Description[81]='is ± 0.03 ml.'
Description[82]=''
Description[83]='5. Sample preparation recovery R. Extraction recovery was determined using a'
Description[84]='CRM with similar composition and phosphorus content. (6.8 g/kg). It was found'
Description[85]='that R = 0.95, u(R) = 0.04. The recovery determined this way takes also to some'
Description[86]='extent into account the uncertainty due to the inhomogeneity of the sample (be'
Description[87]='careful, however, because CRM-s tend to be more homogenous than the usual'
Description[88]='samples).'
Description[89]=''
Description[90]='6. Repeatability of the standard solution measurement. The repeatability was'
Description[91]='determined at two different concentration levels: one near 0.0 AU and the other'
Description[92]='near 1.0 AU. Every time new amount of the sample solution was used and the'
Description[93]='photometric reaction was carried out. This way the determined repeatability'
Description[94]='includes not only the effects coming from the photometer but also the possible'
Description[95]='variations of the chemical reaction (that are far bigger, in fact). It was'
Description[96]='found that the standard uncertainty of repeatability was 0.0012 AU and 0.0021'
Description[97]='AU at absorbances 0.0 and 1.0 AU, respectively.'
Description[98]=''
Description[99]='7. Repeatability of the sample measurement. The repeatability uncertainty of'
Description[100]='the sample measurement is expected to be somewhat higher than the repeatability'
Description[101]='of the standard solution measurement, because various extraneous ions are'
Description[102]='present in the solution. It was found that at 0.5 AU level the repeatability'
Description[103]='uncertainty was 0.0030 AU.'
Description[104]=''
Description[105]='8. Drift of the photometer reading. Drift is more difficult to determine than'
Description[106]='repeatability. The drift is not necessarily the same on different days and if'
Description[107]='the laboratory is not air-conditioned (as is the case in this example) then it'
Description[108]='depends on the season. Based on long-time observations it was concluded that'
Description[109]='the drift of the photometer during 4-5 hours is not ore than 0.002 and 0.003 AU'
Description[110]='at absorbance values 0.0 and 1.0 AU, respectively.'
Description[111]=''
Description[112]='9. Linearity of the calibration graph. It was found that in the concentration'
Description[113]='range 5 .. 40 mg/ml the calibration graph is linear.'
Description[114]=''
Description[115]='10. Temperature in the laboratory. It was found that the temperature in the'
Description[116]='laboratory during the measurement differed from 20 °C not more than ± 3 °C,'
Description[117]='also all solutions and volumetric ware were at that temperature during the'
Description[118]='work. The temperature was constant throughout the work.'

[Model]
Model=150
Model[0]='{ Finding the phosphorus content of the sample using the sample solution concentration}'
Model[1]=''
Model[2]='Q_sample = C_500 * V_500 / (m_sample * R);'
Model[3]=''
Model[4]='{   Volume of the 500 ml volumetric flask used for sample solution preparation.'
Model[5]='    For all volumetric equipment the uncertainty consists of 3 components (on the example of V_500):'
Model[6]='         - calibration uncertainty i.e. the uncertainty of the stated volume of the volumetric vessel (V_500\us\cal);'
Model[7]='         - repeatability of using the volumetric vessel (V_500\us\rep);'
Model[8]='         - uncertainty due to the temperature effect (V_500\us\temp)'
Model[9]='}'
Model[10]=''
Model[11]='V_500 = V_500\us\cal + V_500\us\rep + V_500\us\temp;'
Model[12]='V_500\us\temp = V_500\us\cal * \Delta\t * \gamma\;'
Model[13]=''
Model[14]=''
Model[15]='{ Uncertainty of sample mass m_sample.'
Model[16]='  The uncertainty of mass measurement has 3 uncertainty components (on the example of m_sample):'
Model[17]='          - repeatability of weighing (included in m_sample\us\0);'
Model[18]='          - drift of the balance (m_sample\us\drift);'
Model[19]='          - uncertainty due to rounding of the reading (m_sample\us\round)'
Model[20]='}'
Model[21]=''
Model[22]='m_sample = m_sample\us\0 + m_sample\us\drift + m_sample\us\round;'
Model[23]=''
Model[24]=''
Model[25]=''
Model[26]=''
Model[27]=''
Model[28]='{ Finding the concentration of the sample solution C_500 from the absorbance data. }'
Model[29]=''
Model[30]='C_500 = (A_sample - b_0) / b_1 * (V_sample\us\10 + V_sample\us\reagent) / V_sample\us\10;'
Model[31]=''
Model[32]=''
Model[33]='{    It is assumed that all absorbance measurement results have 3 uncertainty components (on the example of A_sample):'
Model[34]='         - repeatability uncertainty (included in A_sample\us\rep);'
Model[35]='         - uncertainty due to drift (A_sample\us\drift)'
Model[36]='         - uncertainty due to rounding of the reading (A_sample\us\round)'
Model[37]='}'
Model[38]=''
Model[39]=''
Model[40]='A_sample=A_sample\us\rep+A_sample\us\drift+A_sample\us\round+A_sample\us\chemical_drift;'
Model[41]=''
Model[42]=''
Model[43]=''
Model[44]='{ Pipetting the reagent solution: The same pipette was used for pipetting the reagent throughout the work, both for the sample and the standard solutions.'
Model[45]='  Therefore only the quantity representing the repeatability uncertainty contribution changes from one pipettng to another.'
Model[46]='  The V_reagent\us\cal and V_reagent\us\temp are the same for all reagent pipetting operations.'
Model[47]=''
Model[48]='  The same holds for pipetting the sample solution.'
Model[49]='}'
Model[50]=''
Model[51]='V_sample\us\reagent = V_reagent\us\cal + V_sample\us\reagent\us\rep + V_reagent\us\temp;'
Model[52]='V_reagent\us\temp = V_reagent\us\cal * \Delta\t * \gamma\;'
Model[53]=''
Model[54]='V_sample\us\10 = V_10\us\cal + V_sample\us\10\us\rep + V_10\us\temp;'
Model[55]='V_10\us\temp = V_10\us\cal * \Delta\t * \gamma\;'
Model[56]=''
Model[57]=''
Model[58]=''
Model[59]=''
Model[60]=''
Model[61]='{ Linear regression equations}'
Model[62]=''
Model[63]='b_1=(\Sigma\CA - n * AvgC * AvgA) / (\Sigma\CC - n * AvgC * AvgC);'
Model[64]='b_0=AvgA-b_1*AvgC;'
Model[65]=''
Model[66]='\Sigma\CA=C_1*A_1+C_2*A_2+C_3*A_3+C_4*A_4+C_5*A_5;'
Model[67]='AvgC=(C_1+C_2+C_3+C_4+C_5)/n;'
Model[68]='AvgA=(A_1+A_2+A_3+A_4+A_5)/n;'
Model[69]='\Sigma\CC=C_1*C_1+C_2*C_2+C_3*C_3+C_4*C_4+C_5*C_5;'
Model[70]=''
Model[71]=''
Model[72]=''
Model[73]=''
Model[74]='{ Absorbances of the calibration standard solutions }'
Model[75]=''
Model[76]='A_1 = A_1rep + A_1drift + A_1round;'
Model[77]='A_2 = A_2rep + A_2drift + A_2round;'
Model[78]='A_3 = A_3rep + A_3drift + A_3round;'
Model[79]='A_4 = A_4rep + A_4drift + A_4round;'
Model[80]='A_5 = A_5rep + A_5drift + A_5round;'
Model[81]=''
Model[82]=''
Model[83]=''
Model[84]='{ Concentrations of the standard solutions that were actually measured (after the reaction)}'
Model[85]=''
Model[86]='C_1 = C_stock * (V_1\us\stock / V_1\us\100) * V_1\us\10 / (V_1\us\10 + V_1\us\reagent);'
Model[87]='C_2 = C_stock * (V_2\us\stock / V_2\us\100) * V_2\us\10 / (V_2\us\10 + V_2\us\reagent);'
Model[88]='C_3 = C_stock * (V_3\us\stock / V_3\us\100) * V_3\us\10 / (V_3\us\10 + V_3\us\reagent);'
Model[89]='C_4 = C_stock * (V_4\us\stock / V_4\us\100) * V_4\us\10 / (V_4\us\10 + V_4\us\reagent);'
Model[90]='C_5 = C_stock * (V_5\us\stock / V_5\us\100) * V_5\us\10 / (V_5\us\10 + V_5\us\reagent);'
Model[91]=''
Model[92]=''
Model[93]='{ Volumes of the stock solution pipetted for preparing the standard solutions }'
Model[94]=''
Model[95]='V_1\us\stock = V_1\us\stock\us\cal + V_1\us\stock\us\rep + V_1\us\stock\us\temp;'
Model[96]='V_1\us\stock\us\temp = V_1\us\stock\us\cal * \Delta\t * \gamma\;'
Model[97]='V_2\us\stock = V_2\us\stock\us\cal + V_2\us\stock\us\rep + V_2\us\stock\us\temp;'
Model[98]='V_2\us\stock\us\temp = V_2\us\stock\us\cal * \Delta\t * \gamma\;'
Model[99]='V_3\us\stock = V_3\us\stock\us\cal + V_3\us\stock\us\rep + V_3\us\stock\us\temp;'
Model[100]='V_3\us\stock\us\temp = V_3\us\stock\us\cal * \Delta\t * \gamma\;'
Model[101]='V_4\us\stock = V_4\us\stock\us\cal + V_4\us\stock\us\rep + V_4\us\stock\us\temp;'
Model[102]='V_4\us\stock\us\temp = V_4\us\stock\us\cal * \Delta\t * \gamma\;'
Model[103]='V_5\us\stock = V_5\us\stock\us\cal + V_5\us\stock\us\rep + V_5\us\stock\us\temp;'
Model[104]='V_5\us\stock\us\temp = V_5\us\stock\us\cal * \Delta\t * \gamma\;'
Model[105]=''
Model[106]=''
Model[107]='{ Volumes of the 100 ml volumetric flasks }'
Model[108]=''
Model[109]='V_1\us\100 = V_1\us\100\us\cal + V_1\us\100\us\rep + V_1\us\100\us\temp;'
Model[110]='V_1\us\100\us\temp = V_1\us\100\us\cal * \Delta\t * \gamma\;'
Model[111]='V_2\us\100 = V_2\us\100\us\cal + V_2\us\100\us\rep + V_2\us\100\us\temp;'
Model[112]='V_2\us\100\us\temp = V_2\us\100\us\cal * \Delta\t * \gamma\;'
Model[113]='V_3\us\100 = V_3\us\100\us\cal + V_3\us\100\us\rep + V_3\us\100\us\temp;'
Model[114]='V_3\us\100\us\temp = V_3\us\100\us\cal * \Delta\t * \gamma\;'
Model[115]='V_4\us\100 = V_4\us\100\us\cal + V_4\us\100\us\rep + V_4\us\100\us\temp;'
Model[116]='V_4\us\100\us\temp = V_4\us\100\us\cal * \Delta\t * \gamma\;'
Model[117]='V_5\us\100 = V_5\us\100\us\cal + V_5\us\100\us\rep + V_5\us\100\us\temp;'
Model[118]='V_5\us\100\us\temp = V_5\us\100\us\cal * \Delta\t * \gamma\;'
Model[119]=''
Model[120]=''
Model[121]=''
Model[122]='{ Volumes of the solutions pipetted into the reaction flasks }'
Model[123]=''
Model[124]='V_1\us\10 = V_10\us\cal + V_1\us\10\us\rep + V_10\us\temp;'
Model[125]='V_2\us\10 = V_10\us\cal + V_2\us\10\us\rep + V_10\us\temp;'
Model[126]='V_3\us\10 = V_10\us\cal + V_3\us\10\us\rep + V_10\us\temp;'
Model[127]='V_4\us\10 = V_10\us\cal + V_4\us\10\us\rep + V_10\us\temp;'
Model[128]='V_5\us\10 = V_10\us\cal + V_5\us\10\us\rep + V_10\us\temp;'
Model[129]=''
Model[130]=''
Model[131]=''
Model[132]='{ Reagent volumes pipetted into the reaction flasks }'
Model[133]=''
Model[134]='V_1\us\reagent = V_reagent\us\cal + V_1\us\reagent\us\rep + V_reagent\us\temp;'
Model[135]='V_2\us\reagent = V_reagent\us\cal + V_2\us\reagent\us\rep + V_reagent\us\temp;'
Model[136]='V_3\us\reagent = V_reagent\us\cal + V_3\us\reagent\us\rep + V_reagent\us\temp;'
Model[137]='V_4\us\reagent = V_reagent\us\cal + V_4\us\reagent\us\rep + V_reagent\us\temp;'
Model[138]='V_5\us\reagent = V_reagent\us\cal + V_5\us\reagent\us\rep + V_reagent\us\temp;'
Model[139]=''
Model[140]=''
Model[141]=''
Model[142]=''
Model[143]='{ Preparation of the stock solution.}'
Model[144]=''
Model[145]='C_stock = M_P / M_KH2PO4 * P * m_std / V_1000;'
Model[146]=''
Model[147]='m_std = m_std\us\0 + m_std\us\drift + m_std\us\round;'
Model[148]='V_1000 = V_1000\us\cal + V_1000\us\rep + V_1000\us\temp;'
Model[149]='V_1000\us\temp = V_1000\us\cal * \Delta\t * \gamma\;'
Model[150]=''
Model[151]='m_std = m_std\us\0 + m_std\us\drift + m_std\us\round;'
Model[152]='V_1000 = V_1000\us\cal + V_1000\us\rep + V_1000\us\temp;'
Model[153]='V_1000\us\temp = V_1000\us\cal * \Delta\t * \gamma\;'
CE=1
CTC=1

[Components]
CompOrder=0
Comp=130
Comp[0]=Q_sample_
Comp[1]=C_500_
Comp[2]=V_500_
Comp[3]=V_500\us\cal_
Comp[4]=V_500\us\rep_
Comp[5]=V_500\us\temp_
Comp[6]=m_sample_
Comp[7]=R
Comp[8]=m_sample\us\0_
Comp[9]=m_sample\us\drift_
Comp[10]=m_sample\us\round_
Comp[11]=\Delta\t
Comp[12]=\gamma\
Comp[13]=A_sample_
Comp[14]=A_sample\us\rep_
Comp[15]=A_sample\us\drift_
Comp[16]=A_sample\us\round_
Comp[17]=V_sample\us\10_
Comp[18]=V_10\us\cal_
Comp[19]=V_sample\us\10\us\rep_
Comp[20]=V_10\us\temp_
Comp[21]=V_sample\us\reagent_
Comp[22]=V_reagent\us\cal_
Comp[23]=V_sample\us\reagent\us\rep_
Comp[24]=V_reagent\us\temp_
Comp[25]=b_0_
Comp[26]=b_1_
Comp[27]=n
Comp[28]=AvgC
Comp[29]=AvgA
Comp[30]=\Sigma\CC
Comp[31]=\Sigma\CA
Comp[32]=A_1_
Comp[33]=A_2_
Comp[34]=A_3_
Comp[35]=A_4_
Comp[36]=A_5_
Comp[37]=A_1rep_
Comp[38]=A_2rep_
Comp[39]=A_3rep_
Comp[40]=A_4rep_
Comp[41]=A_5rep_
Comp[42]=A_1drift_
Comp[43]=A_2drift_
Comp[44]=A_3drift_
Comp[45]=A_4drift_
Comp[46]=A_5drift_
Comp[47]=A_1round_
Comp[48]=A_2round_
Comp[49]=A_3round_
Comp[50]=A_4round_
Comp[51]=A_5round_
Comp[52]=C_1_
Comp[53]=C_2_
Comp[54]=C_3_
Comp[55]=C_4_
Comp[56]=C_5_
Comp[57]=V_1\us\stock_
Comp[58]=V_1\us\100_
Comp[59]=V_1\us\10_
Comp[60]=V_1\us\reagent_
Comp[61]=V_2\us\stock_
Comp[62]=V_2\us\100_
Comp[63]=V_2\us\10_
Comp[64]=V_2\us\reagent_
Comp[65]=V_3\us\stock_
Comp[66]=V_3\us\100_
Comp[67]=V_3\us\10_
Comp[68]=V_3\us\reagent_
Comp[69]=V_4\us\stock_
Comp[70]=V_4\us\100_
Comp[71]=V_4\us\10_
Comp[72]=V_4\us\reagent_
Comp[73]=V_5\us\stock_
Comp[74]=V_5\us\100_
Comp[75]=V_5\us\10_
Comp[76]=V_5\us\reagent_
Comp[77]=V_1\us\stock\us\cal_
Comp[78]=V_1\us\stock\us\rep_
Comp[79]=V_1\us\stock\us\temp_
Comp[80]=V_2\us\stock\us\cal_
Comp[81]=V_2\us\stock\us\rep_
Comp[82]=V_2\us\stock\us\temp_
Comp[83]=V_3\us\stock\us\cal_
Comp[84]=V_3\us\stock\us\rep_
Comp[85]=V_3\us\stock\us\temp_
Comp[86]=V_4\us\stock\us\cal_
Comp[87]=V_4\us\stock\us\rep_
Comp[88]=V_4\us\stock\us\temp_
Comp[89]=V_5\us\stock\us\cal_
Comp[90]=V_5\us\stock\us\rep_
Comp[91]=V_5\us\stock\us\temp_
Comp[92]=V_1\us\100\us\cal_
Comp[93]=V_1\us\100\us\rep_
Comp[94]=V_1\us\100\us\temp_
Comp[95]=V_2\us\100\us\cal_
Comp[96]=V_2\us\100\us\rep_
Comp[97]=V_2\us\100\us\temp_
Comp[98]=V_3\us\100\us\cal_
Comp[99]=V_3\us\100\us\rep_
Comp[100]=V_3\us\100\us\temp_
Comp[101]=V_4\us\100\us\cal_
Comp[102]=V_4\us\100\us\rep_
Comp[103]=V_4\us\100\us\temp_
Comp[104]=V_5\us\100\us\cal_
Comp[105]=V_5\us\100\us\rep_
Comp[106]=V_5\us\100\us\temp_
Comp[107]=V_1\us\10\us\rep_
Comp[108]=V_2\us\10\us\rep_
Comp[109]=V_3\us\10\us\rep_
Comp[110]=V_4\us\10\us\rep_
Comp[111]=V_5\us\10\us\rep_
Comp[112]=V_1\us\reagent\us\rep_
Comp[113]=V_2\us\reagent\us\rep_
Comp[114]=V_3\us\reagent\us\rep_
Comp[115]=V_4\us\reagent\us\rep_
Comp[116]=V_5\us\reagent\us\rep_
Comp[117]=C_stock_
Comp[118]=M_P_
Comp[119]=M_KH2PO4_
Comp[120]=P
Comp[121]=m_std_
Comp[122]=V_1000_
Comp[123]=m_std\us\0_
Comp[124]=m_std\us\drift_
Comp[125]=m_std\us\round_
Comp[126]=V_1000\us\cal_
Comp[127]=V_1000\us\rep_
Comp[128]=V_1000\us\temp_
Comp[129]=A_sample\us\chemical_drift

[COMP 0]
Type=Result
Definition='Phosphorus content of the feed sample'
Unit='mg/g'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=5.77621346650737
Ustd=0.277169140688161
Neff=83
HB=1
HC=0
HR=1
IO=0

[COMP 1]
Type=Temp
Definition='Phosphorus concentration in the 500 ml flask'
Unit='\mu\g/ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=27.8990532810959
Ustd=0.638192192682331
Neff=8211
HB=0
HC=0
HR=0
IO=0

[COMP 2]
Type=Temp
Definition='Volume of the 500 ml flask used for sample preparation'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=500
Ustd=0.298510189664161
Neff=10000
HB=0
HC=0
HR=0
IO=0

[COMP 3]
Type=TypBRectang
Definition='Volume together with the calibration uncertainty of the 500 ml flask used for sample preparation'
Unit='ml'
Description=0
Vnom=500
Hlim=.4

[COMP 4]
Type=TypBRectang
Definition='Repeatability uncertainty of the volume of the 500 ml flask used for sample preparation'
Unit='ml'
Description=2
Description[0]='If the flask is filled dropwise, then it is not likely, that the uncertainty is'
Description[1]='larger than ± 3 drops. Uncertainty ± 0.03 ml roughly corresponds ± 1 drop.'
Vnom=0
Hlim=.09

[COMP 5]
Type=Temp
Definition='Temperature uncertainty of the volume of the 500 ml flask used for sample preparation'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=0
Ustd=0.181865334794732
Neff=10000
HB=0
HC=0
HR=0
IO=0

[COMP 6]
Type=Temp
Definition='Mass of the sample taken for analysis'
Unit='mg'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=2542.1
Ustd=0.154272486205415
Neff=10000
HB=0
HC=0
HR=0
IO=0

[COMP 7]
Type=TypBNormal
Definition='Recovery factor'
Unit='unitless'
Description=0
Vnom=.95
Uexp=.04
Fcov=1

[COMP 8]
Type=TypBRectang
Definition='Value of the mass of the sample taken for analysis together with repeatability uncertainty of weighing'
Unit='mg'
Description=0
Vnom=2542.1
Hlim=.17

[COMP 9]
Type=TypBRectang
Definition='Drift component of the uncertainty of the mass of the sample taken for analysis'
Unit='mg'
Description=0
Vnom=0
Hlim=.2

[COMP 10]
Type=TypBRectang
Definition='Rounding component of the uncertainty of the mass of the sample taken for analysis'
Unit='mg'
Description=0
Vnom=0
Hlim=.05

[COMP 11]
Type=TypBRectang
Definition='Difference of the laboratory temperature from 20 °C'
Unit='°C'
Description=0
Vnom=0
Hlim=3

[COMP 12]
Type=Const
Definition='Thermal expansion coefficient of water'
Unit='1/°C'
Description=0
Vnom=0.00021

[COMP 13]
Type=Temp
Definition='Absorbance of the sample solution'
Unit='AU'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=0.474
Ustd=0.0105432822213958
Neff=7627
HB=0
HC=0
HR=0
IO=0

[COMP 14]
Type=TypBNormal
Definition='Absorbance value of the sample solution together with its repeatability uncertainty component'
Unit='AU'
Description=0
Vnom=.474
Uexp=.003
Fcov=1

[COMP 15]
Type=TypBRectang
Definition='Uncertainty of the sample solution absorbance due to photometer drift'
Unit='AU'
Description=2
Description[0]='The uncertainty due to drift has been estimated by linear interpolation taking'
Description[1]='into account that at A=0.0 the drift is ±0.002 and at A=1.0 the drift is ±0.003'
Vnom=0
Hlim=.0025

[COMP 16]
Type=TypBRectang
Definition='Uncertainty component of the sample solution absorbance due to rounding'
Unit='AU'
Description=0
Vnom=0
Hlim=0.0005

[COMP 17]
Type=Temp
Definition='Volume of the 10 pipette used for pipetting the sample solution into the reaction flask'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=10
Ustd=0.0437404846795277
Neff=71
HB=0
HC=0
HR=0
IO=0

[COMP 18]
Type=TypBRectang
Definition='Value and the calibration uncertainty of the volume of the 10 ml pipette used for pipetting the sample solution into the reaction flask'
Unit='ml'
Description=0
Vnom=10
Hlim=0.03

[COMP 19]
Type=TypBNormal
Definition='Repeatability uncertainty  of the 10 ml pipette used for pipetting the sample solution into the reaction flask'
Unit='ml'
Description=2
Description[0]='Repeatability standard uncertainty of pipetting is assumed 0.4% of the pipette'
Description[1]='volume throughout.'
Vnom=0
Uexp=.04
Fcov=1

[COMP 20]
Type=Temp
Definition='Temperature uncertainty  of the 10 ml pipette used for pipetting the sample solution into the reaction flask'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=0
Ustd=0.00363730669589464
Neff=10000
HB=0
HC=0
HR=0
IO=0

[COMP 21]
Type=Temp
Definition='Volume of the 10 pipette used for pipetting the reagent solution into the reaction flask for the measurement of the sample'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=10
Ustd=0.0437404846795277
Neff=71
HB=0
HC=0
HR=0
IO=0

[COMP 22]
Type=TypBRectang
Definition='Value and the calibration uncertainty of the 10 ml pipette used for pipetting the reagent solution into the reaction flask'
Unit='ml'
Description=0
Vnom=10
Hlim=.03

[COMP 23]
Type=TypBNormal
Definition='Repeatability uncertainty  of the 10 ml pipette used for pipetting the reagent solution into the reaction flask'
Unit='ml'
Description=2
Description[0]='Repeatability standard uncertainty of pipetting is assumed 0.4% of the pipette'
Description[1]='volume throughout.'
Vnom=0
Uexp=.04
Fcov=1

[COMP 24]
Type=Temp
Definition='Temperature uncertainty  of the 10 ml pipette used for pipetting the reagent solution into the reaction flask'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=0
Ustd=0.00363730669589464
Neff=10000
HB=0
HC=0
HR=0
IO=0

[COMP 25]
Type=Temp
Definition='Intercept of the calibration line'
Unit='AU'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=0.000317073170731707
Ustd=0.00224169435276945
Neff=1096
HB=0
HC=0
HR=0
IO=0

[COMP 26]
Type=Temp
Definition='Slope of the calibration line'
Unit='AU·ml/\mu\g'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=0.0339569176098337
Ustd=0.000257264210440829
Neff=631
HB=0
HC=0
HR=0
IO=0

[COMP 27]
Type=Const
Definition='Number of points on the calibration line'
Unit='unitless'
Description=0
Vnom=5

[COMP 28]
Type=Temp
Definition='Interim quantity for regression analysis'
Unit='\mu\g/ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=10.6158907286942
Ustd=0.0376734860913132
Neff=945
HB=0
HC=0
HR=0
IO=0

[COMP 29]
Type=Temp
Definition='Interim quantity for regression analysis'
Unit='AU'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=0.3608
Ustd=0.000931020944984591
Neff=767
HB=0
HC=0
HR=0
IO=0

[COMP 30]
Type=Temp
Definition='Interim quantity for regression analysis'
Unit='(\mu\g/ml)²'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=773.035909954238
Ustd=6.19981849348217
Neff=519
HB=0
HC=0
HR=0
IO=0

[COMP 31]
Type=Temp
Definition='Interim quantity for regression analysis'
Unit='AU·\mu\g/ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=26.2667467744263
Ustd=0.123027944726767
Neff=815
HB=0
HC=0
HR=0
IO=0

[COMP 32]
Type=Temp
Definition='Absorbance of the 1. calibration standard solution'
Unit='AU'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=0.086
Ustd=0.0017625738755203
Neff=168
HB=0
HC=0
HR=0
IO=0

[COMP 33]
Type=Temp
Definition='Absorbance of the 2. calibration standard solution'
Unit='AU'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=0.173
Ustd=0.0019122412679018
Neff=174
HB=0
HC=0
HR=0
IO=0

[COMP 34]
Type=Temp
Definition='Absorbance of the 3. calibration standard solution'
Unit='AU'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=0.341
Ustd=0.00202402239776804
Neff=165
HB=0
HC=0
HR=0
IO=0

[COMP 35]
Type=Temp
Definition='Absorbance of the 4. calibration standard solution'
Unit='AU'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=0.518
Ustd=0.00224870333006972
Neff=153
HB=0
HC=0
HR=0
IO=0

[COMP 36]
Type=Temp
Definition='Absorbance of the 5. calibration standard solution'
Unit='AU'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=0.686
Ustd=0.0023986107090008
Neff=157
HB=0
HC=0
HR=0
IO=0

[COMP 37]
Type=TypBNormal
Definition='Absorbance value and the repeatability uncertainty of the 1. calibration standard solution'
Unit='AU'
Description=3
Description[0]='The uncertainty due to repeatability has been estimated by linear interpolation'
Description[1]='taking into account that at A=0.0 the standard uncertainty due to repeatability'
Description[2]='is 0.0005 AU and at A=1.0 it is 0.0011'
Vnom=.086
Uexp=.0013
Fcov=1

[COMP 38]
Type=TypBNormal
Definition='Absorbance value and the repeatability uncertainty of the 2. calibration standard solution'
Unit='AU'
Description=3
Description[0]='The uncertainty due to repeatability has been estimated by linear interpolation'
Description[1]='taking into account that at A=0.0 the standard uncertainty due to repeatability'
Description[2]='is 0.0005 AU and at A=1.0 it is 0.0011'
Vnom=.173
Uexp=.0014
Fcov=1

[COMP 39]
Type=TypBNormal
Definition='Absorbance value and the repeatability uncertainty of the 3. calibration standard solution'
Unit='AU'
Description=3
Description[0]='The uncertainty due to repeatability has been estimated by linear interpolation'
Description[1]='taking into account that at A=0.0 the standard uncertainty due to repeatability'
Description[2]='is 0.0005 AU and at A=1.0 it is 0.0011'
Vnom=.341
Uexp=.0015
Fcov=1

[COMP 40]
Type=TypBNormal
Definition='Absorbance value and the repeatability uncertainty of the 4. calibration standard solution'
Unit='AU'
Description=3
Description[0]='The uncertainty due to repeatability has been estimated by linear interpolation'
Description[1]='taking into account that at A=0.0 the standard uncertainty due to repeatability'
Description[2]='is 0.0005 AU and at A=1.0 it is 0.0011'
Vnom=.518
Uexp=.0017
Fcov=1

[COMP 41]
Type=TypBNormal
Definition='Absorbance value and the repeatability uncertainty of the 5. calibration standard solution'
Unit='AU'
Description=3
Description[0]='The uncertainty due to repeatability has been estimated by linear interpolation'
Description[1]='taking into account that at A=0.0 the standard uncertainty due to repeatability'
Description[2]='is 0.0005 AU and at A=1.0 it is 0.0011'
Vnom=.686
Uexp=.0018
Fcov=1

[COMP 42]
Type=TypBRectang
Definition='Drift uncertainty component of the absorbance value of the 1. calibration standard solution'
Unit='AU'
Description=2
Description[0]='The uncertainty due to drift has been estimated by linear interpolation taking'
Description[1]='into account that at A=0.0 the drift is ±0.002 and at A=1.0 the drift is ±0.003'
Vnom=0
Hlim=.0020

[COMP 43]
Type=TypBRectang
Definition='Drift uncertainty component of the absorbance value of the 2. calibration standard solution'
Unit='AU'
Description=2
Description[0]='The uncertainty due to drift has been estimated by linear interpolation taking'
Description[1]='into account that at A=0.0 the drift is ±0.002 and at A=1.0 the drift is ±0.003'
Vnom=0
Hlim=.0022

[COMP 44]
Type=TypBRectang
Definition='Drift uncertainty component of the absorbance value of the 3. calibration standard solution'
Unit='AU'
Description=2
Description[0]='The uncertainty due to drift has been estimated by linear interpolation taking'
Description[1]='into account that at A=0.0 the drift is ±0.002 and at A=1.0 the drift is ±0.003'
Vnom=0
Hlim=.0023

[COMP 45]
Type=TypBRectang
Definition='Drift uncertainty component of the absorbance value of the 4. calibration standard solution'
Unit='AU'
Description=2
Description[0]='The uncertainty due to drift has been estimated by linear interpolation taking'
Description[1]='into account that at A=0.0 the drift is ±0.002 and at A=1.0 the drift is ±0.003'
Vnom=0
Hlim=.0025

[COMP 46]
Type=TypBRectang
Definition='Drift uncertainty component of the absorbance value of the 5. calibration standard solution'
Unit='AU'
Description=2
Description[0]='The uncertainty due to drift has been estimated by linear interpolation taking'
Description[1]='into account that at A=0.0 the drift is ±0.002 and at A=1.0 the drift is ±0.003'
Vnom=0
Hlim=.0027

[COMP 47]
Type=TypBRectang
Definition='Rounding uncertainty component of the absorbance value of the 1. calibration standard solution'
Unit='AU'
Description=0
Vnom=0
Hlim=.0005

[COMP 48]
Type=TypBRectang
Definition='Rounding uncertainty component of the absorbance value of the 2. calibration standard solution'
Unit='AU'
Description=0
Vnom=0
Hlim=.0005

[COMP 49]
Type=TypBRectang
Definition='Rounding uncertainty component of the absorbance value of the 3. calibration standard solution'
Unit='AU'
Description=0
Vnom=0
Hlim=.0005

[COMP 50]
Type=TypBRectang
Definition='Rounding uncertainty component of the absorbance value of the 4. calibration standard solution'
Unit='AU'
Description=0
Vnom=0
Hlim=.0005

[COMP 51]
Type=TypBRectang
Definition='Rounding uncertainty component of the absorbance value of the 5. calibration standard solution'
Unit='AU'
Description=0
Vnom=0
Hlim=.0005

[COMP 52]
Type=Temp
Definition='Concentration of the 1. calibration standard solution'
Unit='\mu\g/ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=2.52759303064149
Ustd=0.0245962980907994
Neff=1556
HB=0
HC=0
HR=0
IO=0

[COMP 53]
Type=Temp
Definition='Concentration of the 2. calibration standard solution'
Unit='\mu\g/ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=5.05518606128297
Ustd=0.0400269224826464
Neff=682
HB=0
HC=0
HR=0
IO=0

[COMP 54]
Type=Temp
Definition='Concentration of the 3. calibration standard solution'
Unit='\mu\g/ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=10.1103721225659
Ustd=0.0701278492260107
Neff=401
HB=0
HC=0
HR=0
IO=0

[COMP 55]
Type=Temp
Definition='Concentration of the 4. calibration standard solution'
Unit='\mu\g/ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=15.1655581838489
Ustd=0.093110347626853
Neff=246
HB=0
HC=0
HR=0
IO=0

[COMP 56]
Type=Temp
Definition='Concentration of the 5. calibration standard solution'
Unit='\mu\g/ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=20.2207442451319
Ustd=0.124147130169137
Neff=246
HB=0
HC=0
HR=0
IO=0

[COMP 57]
Type=Temp
Definition='Volume of the stock solution pipetted for preparing the standard solution No 1.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=0.5
Ustd=0.00451291572415587
Neff=1296
HB=0
HC=0
HR=0
IO=0

[COMP 58]
Type=Temp
Definition='Volume of the 100 ml volumetric flask used for preparing the standard solution No 1.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=100
Ustd=0.184453246108601
Neff=10000
HB=0
HC=0
HR=0
IO=0

[COMP 59]
Type=Temp
Definition='Volume of the standard solution No 1. pipetted into the reaction flask '
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=10
Ustd=0.0437404846795277
Neff=71
HB=0
HC=0
HR=0
IO=0

[COMP 60]
Type=Temp
Definition='Volume of the reagent solution pipetted into the reaction flask for measurement of the standard solution No 1.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=10
Ustd=0.0437404846795277
Neff=71
HB=0
HC=0
HR=0
IO=0

[COMP 61]
Type=Temp
Definition='Volume of the stock solution pipetted for preparing the standard solution No 2.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=1
Ustd=0.00703318088302393
Neff=477
HB=0
HC=0
HR=0
IO=0

[COMP 62]
Type=Temp
Definition='Volume of the 100 ml volumetric flask used for preparing the standard solution No 2.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=100
Ustd=0.184453246108601
Neff=10000
HB=0
HC=0
HR=0
IO=0

[COMP 63]
Type=Temp
Definition='Volume of the standard solution No 2. pipetted into the reaction flask '
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=10
Ustd=0.0437404846795277
Neff=71
HB=0
HC=0
HR=0
IO=0

[COMP 64]
Type=Temp
Definition='Volume of the reagent solution pipetted into the reaction flask for measurement of the standard solution No 2.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=10
Ustd=0.0437404846795277
Neff=71
HB=0
HC=0
HR=0
IO=0

[COMP 65]
Type=Temp
Definition='Volume of the stock solution pipetted for preparing the standard solution No 3.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=2
Ustd=0.0118122478809073
Neff=237
HB=0
HC=0
HR=0
IO=0

[COMP 66]
Type=Temp
Definition='Volume of the 100 ml volumetric flask used for preparing the standard solution No 3.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=100
Ustd=0.184453246108601
Neff=10000
HB=0
HC=0
HR=0
IO=0

[COMP 67]
Type=Temp
Definition='Volume of the standard solution No 3. pipetted into the reaction flask '
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=10
Ustd=0.0437404846795277
Neff=71
HB=0
HC=0
HR=0
IO=0

[COMP 68]
Type=Temp
Definition='Volume of the reagent solution pipetted into the reaction flask for measurement of the standard solution No 3.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=10
Ustd=0.0437404846795277
Neff=71
HB=0
HC=0
HR=0
IO=0

[COMP 69]
Type=Temp
Definition='Volume of the stock solution pipetted for preparing the standard solution No 4.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=3
Ustd=0.0148388240773991
Neff=116
HB=0
HC=0
HR=0
IO=0

[COMP 70]
Type=Temp
Definition='Volume of the 100 ml volumetric flask used for preparing the standard solution No 4.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=100
Ustd=0.184453246108601
Neff=10000
HB=0
HC=0
HR=0
IO=0

[COMP 71]
Type=Temp
Definition='Volume of the standard solution No 4. pipetted into the reaction flask'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=10
Ustd=0.0437404846795277
Neff=71
HB=0
HC=0
HR=0
IO=0

[COMP 72]
Type=Temp
Definition='Volume of the reagent solution pipetted into the reaction flask for measurement of the standard solution No 4.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=10
Ustd=0.0437404846795277
Neff=71
HB=0
HC=0
HR=0
IO=0

[COMP 73]
Type=Temp
Definition='Volume of the stock solution pipetted for preparing the standard solution No 5.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=4
Ustd=0.0197850987698655
Neff=116
HB=0
HC=0
HR=0
IO=0

[COMP 74]
Type=Temp
Definition='Volume of the 100 ml volumetric flask used for preparing the standard solution No 5.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=100
Ustd=0.184453246108601
Neff=10000
HB=0
HC=0
HR=0
IO=0

[COMP 75]
Type=Temp
Definition='Volume of the standard solution No 5. pipetted into the reaction flask '
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=10
Ustd=0.0437404846795277
Neff=71
HB=0
HC=0
HR=0
IO=0

[COMP 76]
Type=Temp
Definition='Volume of the reagent solution pipetted into the reaction flask for measurement of the standard solution No 5.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=10
Ustd=0.0437404846795277
Neff=71
HB=0
HC=0
HR=0
IO=0

[COMP 77]
Type=TypBRectang
Definition='Value and the calibration component of uncertainty of the volume of the stock solution pipetted into the 100 ml flask for preparing the standard solution No 1.'
Unit='ml'
Description=0
Vnom=.5
Hlim=.007

[COMP 78]
Type=TypBNormal
Definition='Repeatability component of uncertainty of the volume of the stock solution pipetted into the 100 ml flask for preparing the standard solution No 1.'
Unit='ml'
Description=2
Description[0]='Repeatability standard uncertainty of pipetting is assumed 0.4% of the pipette'
Description[1]='volume throughout.'
Vnom=0
Uexp=.002
Fcov=1

[COMP 79]
Type=Temp
Definition='Temperature component of uncertainty of the volume of the stock solution pipetted into the 100 ml flask for preparing the standard solution No 1.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=0
Ustd=0.000181865334794732
Neff=10000
HB=0
HC=0
HR=0
IO=0

[COMP 80]
Type=TypBRectang
Definition='Value and the calibration component of uncertainty of the volume of the stock solution pipetted into the 100 ml flask for preparing the standard solution No 2.'
Unit='ml'
Description=0
Vnom=1
Hlim=.010

[COMP 81]
Type=TypBNormal
Definition='Repeatability component of uncertainty of the volume of the stock solution pipetted into the 100 ml flask for preparing the standard solution No 2.'
Unit='ml'
Description=2
Description[0]='Repeatability standard uncertainty of pipetting is assumed 0.4% of the pipette'
Description[1]='volume throughout.'
Vnom=0
Uexp=.004
Fcov=1

[COMP 82]
Type=Temp
Definition='Temperature component of uncertainty of the volume of the stock solution pipetted into the 100 ml flask for preparing the standard solution No 2.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=0
Ustd=0.000363730669589464
Neff=10000
HB=0
HC=0
HR=0
IO=0

[COMP 83]
Type=TypBRectang
Definition='Value and the calibration component of uncertainty of the volume of the stock solution pipetted into the 100 ml flask for preparing the standard solution No 3.'
Unit='ml'
Description=0
Vnom=2
Hlim=.015

[COMP 84]
Type=TypBNormal
Definition='Repeatability component of uncertainty of the volume of the stock solution pipetted into the 100 ml flask for preparing the standard solution No 3.'
Unit='ml'
Description=2
Description[0]='Repeatability standard uncertainty of pipetting is assumed 0.4% of the pipette'
Description[1]='volume throughout.'
Vnom=0
Uexp=.008
Fcov=1

[COMP 85]
Type=Temp
Definition='Temperature component of uncertainty of the volume of the stock solution pipetted into the 100 ml flask for preparing the standard solution No 3.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=0
Ustd=0.000727461339178928
Neff=10000
HB=0
HC=0
HR=0
IO=0

[COMP 86]
Type=TypBRectang
Definition='Value and the calibration component of uncertainty of the volume of the stock solution pipetted into the 100 ml flask for preparing the standard solution No 4.'
Unit='ml'
Description=0
Vnom=3
Hlim=.015

[COMP 87]
Type=TypBNormal
Definition='Repeatability component of uncertainty of the volume of the stock solution pipetted into the 100 ml flask for preparing the standard solution No 4.'
Unit='ml'
Description=2
Description[0]='Repeatability standard uncertainty of pipetting is assumed 0.4% of the pipette'
Description[1]='volume throughout.'
Vnom=0
Uexp=.012
Fcov=1

[COMP 88]
Type=Temp
Definition='Temperature component of uncertainty of the volume of the stock solution pipetted into the 100 ml flask for preparing the standard solution No 4.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=0
Ustd=0.00109119200876839
Neff=10000
HB=0
HC=0
HR=0
IO=0

[COMP 89]
Type=TypBRectang
Definition='Value and the calibration component of uncertainty of the volume of the stock solution pipetted into the 100 ml flask for preparing the standard solution No 5.'
Unit='ml'
Description=0
Vnom=4
Hlim=.02

[COMP 90]
Type=TypBNormal
Definition='Repeatability component of uncertainty of the volume of the stock solution pipetted into the 100 ml flask for preparing the standard solution No 5.'
Unit='ml'
Description=2
Description[0]='Repeatability standard uncertainty of pipetting is assumed 0.4% of the pipette'
Description[1]='volume throughout.'
Vnom=0
Uexp=.016
Fcov=1

[COMP 91]
Type=Temp
Definition='Temperature component of uncertainty of the volume of the stock solution pipetted into the 100 ml flask for preparing the standard solution No 5.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=0
Ustd=0.00145492267835786
Neff=10000
HB=0
HC=0
HR=0
IO=0

[COMP 92]
Type=TypBRectang
Definition='Value and the calibration component of uncertainty of the volume of the 100 ml flask for preparing the standard solution No 1.'
Unit='ml'
Description=0
Vnom=100
Hlim=.3

[COMP 93]
Type=TypBRectang
Definition='Repeatability component of uncertainty of the volume of the 100 ml flask for preparing the standard solution No 1.'
Unit='ml'
Description=2
Description[0]='If the flask is filled dropwise, then it is not likely, that the uncertainty is'
Description[1]='larger than ± 3 drops. Uncertainty ± 0.09 ml roughly corresponds ± 3 drop.'
Vnom=0
Hlim=.09

[COMP 94]
Type=Temp
Definition='Temperature component of uncertainty of the volume of the 100 ml flask for preparing the standard solution No 1.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=0
Ustd=0.0363730669589464
Neff=10000
HB=0
HC=0
HR=0
IO=0

[COMP 95]
Type=TypBRectang
Definition='Value and the calibration component of uncertainty of the volume of the 100 ml flask for preparing the standard solution No 2.'
Unit='ml'
Description=0
Vnom=100
Hlim=.3

[COMP 96]
Type=TypBRectang
Definition='Repeatability component of uncertainty of the volume of the 100 ml flask for preparing the standard solution No 2.'
Unit='ml'
Description=2
Description[0]='If the flask is filled dropwise, then it is not likely, that the uncertainty is'
Description[1]='larger than ± 3 drops. Uncertainty ± 0.09 ml roughly corresponds ± 3 drops.'
Vnom=0
Hlim=.09

[COMP 97]
Type=Temp
Definition='Temperature component of uncertainty of the volume of the 100 ml flask for preparing the standard solution No 2.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=0
Ustd=0.0363730669589464
Neff=10000
HB=0
HC=0
HR=0
IO=0

[COMP 98]
Type=TypBRectang
Definition='Value and the calibration component of uncertainty of the volume of the 100 ml flask for preparing the standard solution No 3.'
Unit='ml'
Description=0
Vnom=100
Hlim=.3

[COMP 99]
Type=TypBRectang
Definition='Repeatability component of uncertainty of the volume of the 100 ml flask for preparing the standard solution No 3.'
Unit='ml'
Description=2
Description[0]='If the flask is filled dropwise, then it is not likely, that the uncertainty is'
Description[1]='larger than ± 3 drops. Uncertainty ± 0.09 ml roughly corresponds ± 3 drops.'
Vnom=0
Hlim=.09

[COMP 100]
Type=Temp
Definition='Temperature component of uncertainty of the volume of the 100 ml flask for preparing the standard solution No 3.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=0
Ustd=0.0363730669589464
Neff=10000
HB=0
HC=0
HR=0
IO=0

[COMP 101]
Type=TypBRectang
Definition='Value and the calibration component of uncertainty of the volume of the 100 ml flask for preparing the standard solution No 4.'
Unit='ml'
Description=0
Vnom=100
Hlim=.3

[COMP 102]
Type=TypBRectang
Definition='Repeatability component of uncertainty of the volume of the 100 ml flask for preparing the standard solution No 4.'
Unit='ml'
Description=2
Description[0]='If the flask is filled dropwise, then it is not likely, that the uncertainty is'
Description[1]='larger than ± 3 drop. Uncertainty ± 0.09 ml roughly corresponds ± 3 drops.'
Vnom=0
Hlim=.09

[COMP 103]
Type=Temp
Definition='Temperature component of uncertainty of the volume of the 100 ml flask for preparing the standard solution No 4.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=0
Ustd=0.0363730669589464
Neff=10000
HB=0
HC=0
HR=0
IO=0

[COMP 104]
Type=TypBRectang
Definition='Value and the calibration component of uncertainty of the volume of the 100 ml flask for preparing the standard solution No 5.'
Unit='ml'
Description=0
Vnom=100
Hlim=.3

[COMP 105]
Type=TypBRectang
Definition='Repeatability component of uncertainty of the volume of the 100 ml flask for preparing the standard solution No 5.'
Unit='ml'
Description=2
Description[0]='If the flask is filled dropwise, then it is not likely, that the uncertainty is'
Description[1]='larger than ± 3 drops. Uncertainty ± 0.09 ml roughly corresponds ± 3 drops.'
Vnom=0
Hlim=.09

[COMP 106]
Type=Temp
Definition='Temperature component of uncertainty of the volume of the 100 ml flask for preparing the standard solution No 5.'
Unit='ml'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=0
Ustd=0.0363730669589464
Neff=10000
HB=0
HC=0
HR=0
IO=0

[COMP 107]
Type=TypBNormal
Definition='Repeatability component of uncertainty of the volume of the standard solution No 1. pipetted into the reaction flask'
Unit='ml'
Description=2
Description[0]='Repeatability standard uncertainty of pipetting is assumed 0.4% of the pipette'
Description[1]='volume throughout.'
Vnom=0
Uexp=.04
Fcov=1

[COMP 108]
Type=TypBNormal
Definition='Repeatability component of uncertainty of the volume of the standard solution No 2. pipetted into the reaction flask'
Unit='ml'
Description=2
Description[0]='Repeatability standard uncertainty of pipetting is assumed 0.4% of the pipette'
Description[1]='volume throughout.'
Vnom=0
Uexp=.04
Fcov=1

[COMP 109]
Type=TypBNormal
Definition='Repeatability component of uncertainty of the volume of the standard solution No 3. pipetted into the reaction flask'
Unit='ml'
Description=2
Description[0]='Repeatability standard uncertainty of pipetting is assumed 0.4% of the pipette'
Description[1]='volume throughout.'
Vnom=0
Uexp=.04
Fcov=1

[COMP 110]
Type=TypBNormal
Definition='Repeatability component of uncertainty of the volume of the standard solution No 4. pipetted into the reaction flask'
Unit='ml'
Description=2
Description[0]='Repeatability standard uncertainty of pipetting is assumed 0.4% of the pipette'
Description[1]='volume throughout.'
Vnom=0
Uexp=.04
Fcov=1

[COMP 111]
Type=TypBNormal
Definition='Repeatability component of uncertainty of the volume of the standard solution No 5. pipetted into the reaction flask'
Unit='ml'
Description=2
Description[0]='Repeatability standard uncertainty of pipetting is assumed 0.4% of the pipette'
Description[1]='volume throughout.'
Vnom=0
Uexp=.04
Fcov=1

[COMP 112]
Type=TypBNormal
Definition='Repeatability component of uncertainty of the volume of the reagent solution pipetted into the reaction flask for measuring the standard solution No 1.'
Unit='ml'
Description=2
Description[0]='Repeatability standard uncertainty of pipetting is assumed 0.4% of the pipette'
Description[1]='volume throughout.'
Vnom=0
Uexp=.04
Fcov=1

[COMP 113]
Type=TypBNormal
Definition='Repeatability component of uncertainty of the volume of the reagent solution pipetted into the reaction flask for measuring the standard solution No 2.'
Unit='ml'
Description=2
Description[0]='Repeatability standard uncertainty of pipetting is assumed 0.4% of the pipette'
Description[1]='volume throughout.'
Vnom=0
Uexp=.04
Fcov=1

[COMP 114]
Type=TypBNormal
Definition='Repeatability component of uncertainty of the volume of the reagent solution pipetted into the reaction flask for measuring the standard solution No 3.'
Unit='ml'
Description=2
Description[0]='Repeatability standard uncertainty of pipetting is assumed 0.4% of the pipette'
Description[1]='volume throughout.'
Vnom=0
Uexp=.04
Fcov=1

[COMP 115]
Type=TypBNormal
Definition='Repeatability component of uncertainty of the volume of the reagent solution pipetted into the reaction flask for measuring the standard solution No 4.'
Unit='ml'
Description=2
Description[0]='Repeatability standard uncertainty of pipetting is assumed 0.4% of the pipette'
Description[1]='volume throughout.'
Vnom=0
Uexp=.04
Fcov=1

[COMP 116]
Type=TypBNormal
Definition='Repeatability component of uncertainty of the volume of the reagent solution pipetted into the reaction flask for measuring the standard solution No 5.'
Unit='ml'
Description=2
Description[0]='Repeatability standard uncertainty of pipetting is assumed 0.4% of the pipette'
Description[1]='volume throughout.'
Vnom=0
Uexp=.04
Fcov=1

[COMP 117]
Type=Temp
Definition='Concentration of the phosphorus stock solution'
Unit='mg/l'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=1011.03721225659
Ustd=0.777367711743514
Neff=10000
HB=0
HC=0
HR=0
IO=0

[COMP 118]
Type=Const
Definition='Atomic mass of Phosphorus'
Unit='g/mol'
Description=0
Vnom=30.97

[COMP 119]
Type=Const
Definition='Molar mass of the standard substance KH2PO4'
Unit='g/mol'
Description=0
Vnom=136.09

[COMP 120]
Type=TypBRectang
Definition='Purity of the standard substance KH2PO4'
Unit='unitless'
Description=0
Vnom=.999
Hlim=.001

[COMP 121]
Type=Temp
Definition='Mass of the standard substance taken for preparation of the stock solution'
Unit='mg'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=4447.2
Ustd=0.207525098883645
Neff=111
HB=0
HC=0
HR=0
IO=0

[COMP 122]
Type=Temp
Definition='Volume of the 1 litre volumetric flask used for preparation of the stock solution'
Unit='l'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=1
Ustd=0.000504975246918104
Neff=10000
HB=0
HC=0
HR=0
IO=0

[COMP 123]
Type=TypBNormal
Definition='Value of the mass of the standard substance together with repeatability uncertainty of weighing'
Unit='mg'
Description=0
Vnom=4447.2
Uexp=.17
Fcov=1

[COMP 124]
Type=TypBRectang
Definition='Drift component of the uncertainty of the mass of the standard substance'
Unit='mg'
Description=0
Vnom=0
Hlim=.2

[COMP 125]
Type=TypBRectang
Definition='Rounding component of the uncertainty of the mass of the standard substance'
Unit='mg'
Description=0
Vnom=0
Hlim=.05

[COMP 126]
Type=TypBRectang
Definition='Volume together with the calibration uncertainty of the 1000 ml flask used for preparation of the stock solution'
Unit='l'
Description=0
Vnom=1
Hlim=.0006

[COMP 127]
Type=TypBRectang
Definition='Repeatability uncertainty of the volume of the 1000 ml flask used for preparation of the stock solution'
Unit='l'
Description=2
Description[0]='If the flask is filled dropwise, then it is not likely, that the uncertainty is'
Description[1]='larger than ± 3 drops. Uncertainty ± 0.09 ml roughly corresponds ± 3 drops.'
Vnom=0
Hlim=.00009

[COMP 128]
Type=Temp
Definition='Temperature uncertainty of the volume of the 1000 ml flask used for preparation of the stock solution'
Unit='l'
Description=0
Fcov=2
NomUnit=
UncUnit=
CovID=0
UncID=0
Vnom=0
Ustd=0.000363730669589464
Neff=10000
HB=0
HC=0
HR=0
IO=0

[Correlations]
Description=0

[COMP 129]
Type=TypBRectang
Definition='Uncertainty component of the sample solution absorbance due to chemical drift'
Unit='AU'
Description=0
Vnom=0
Hlim=0,01732